Both Co content and nanowire growth rate vary quasi-linearly with the deposition potential. Based on this relation, the desired Co-Ni composition in each individual segment can be simply controlled by properly choosing the deposition potential. SAED allows distinguishing AG-881 supplier between the structures of both nanowire segments, being hcp
for the Co85Ni15 segment, while fcc for the Co54Ni46 one, due to the influence of higher presence of fcc Ni in the alloy rather than changes induced during the electrodeposition dynamics. This technique allows not only for tuning the composition of the nanowires but also their crystalline structure in each different nanowire segments, AZD5363 which also affects the magnetic behavior making this system magnetically isotropic. Acknowledgments The financial support from EU-Nanomagma under FP7-214107-2, LEXI-Spintronic funded by the State of Hamburg and Spanish MICINN under research projects MAT2009-13108-C02-01 and MAT2010-20798-C05-04 is acknowledged. The partial support from the Mexican Council of Science and Technology (CONACYT) and Universidad
Autónoma de Nuevo León under research projects CB-179486 and PAICYT-CE793-11 is also acknowledged. Victor Vega is grateful to the German Academic Exchange Service (DAAD) and University of Oviedo for the grants supporting his internships. Javier García thanks FICyT for his Severo Ochoa fellowship. Scientific support from the University of Oviedo SCT is also recognized. References 1. Arico AS, Bruce Akt inhibitor P, Scrosati B, Tarascon J-M, van Schalkwijk W: Nanostructured materials for advanced energy conversion and storage devices. Nature Mater 2005, 4:366–377.CrossRef 2. Rao CNR, Deepak FL, Gundiah G, Govindaraj A: Inorganic nanowires. Progress in Solid State Chemistry 2003, 31:5–147.CrossRef 3. Rao CNR, Govindaraj A: Synthesis of inorganic nanotubes. Adv Mater 2009, 21:4208–4233.CrossRef 4. Hangarter CM, Lee Y-I, Hernandez Cediranib (AZD2171) SC, Y-h C, Myung NV:
Nanopeapods by galvanic displacement reaction. Angew Chem Int Ed 2010, 49:7081–7085.CrossRef 5. Li X, Wang Y, Song G, Peng Z, Yu Y, She X, Li J: Synthesis and growth mechanism of Ni nanotubes and nanowires. Nanoscale Res Lett 2009, 4:1015–1020.CrossRef 6. Proenca MP, Sousa CT, Ventura J, Vazquez M, Araujo JP: Distinguishing nanowire and nanotube formation by the deposition current transients. Nanoscale Res Lett 2012, 7:280.CrossRef 7. Masuda H, Fukuda K: Ordered metal nanohole arrays made by a two-step replication of honeycomb structures of anodic alumina. Science 1995, 268:1466–1468.CrossRef 8. Nielsch K, Müller F, Li A-P, Gösele U: Uniform nickel deposition into ordered alumina pores by pulsed electrodeposition. Adv Mater 2000, 12:582–586.CrossRef 9.